The effects of emulsifier type,phase ratio,and homogenization methods on stability of the double emulsion

The double emulsion technology has a potential effect on the development of diversity and quality of functional foods by means of decreasing oil or salt concentration, encapsulating and controlling release of valuable components. In this study, it was aimed to formulate stable double emulsions to be used in food systems. W1/O ratios of primary emulsions, stabilized by polyglycerol polyricinoleate (PGPR), were designed as 2:8 and 4:6, and (W1/O)/W2 ratios of the double emulsions were used as 2:8 and 4:6. W/O/W phase ratios, homogenization methods applied to primary emulsion (high-speed homogenization, ultrasonic homogenization), and emulsifier types used in W2 phase [sodium caseinate (SC), xanthan gum, lecithin-whey protein concentrate] were used as independent variables. Particle size and distributions, stability, encapsulation efficiency (EE), rheological properties, long-term stability, and morphological properties of the double emulsions were investigated.

The double emulsions prepared with SC and (W1/O)/W2 ratio of 4:6, were found to have the higher stability values, higher apparent viscosity, and lower particle size. High-speed homogenization applied to primary emulsion reduced particle size of the double emulsion and increased apparent viscosity, but did not affect stability and EE of the double emulsions, significantly.     

Conventional and microwave irradiated synthesis,biological activity evaluation and molecular docking studies of highly substituted piperazine-azole hybrids

Azole derivatives(3,6) obtained starting from 1-(2-methoxyphenyl) piperazine were converted to the corresponding Mannich bases containing β-lactame or flouroquinolone core via a one pot three component reaction.The synthesis of conazole analogues was carried out starting from triazoles by three steps.Reactions were carried out under conventional and microwave mediated conditions.All the newly synthesized compounds were screened for their antimicrobial,enzyme inhibition and antioxidant activity,and most of them displayed good-moderate activity.Binding affinities and non-covalent interactions between enzyme-ligand complexes were predicted with molecular docking method at molecular level.Docking results complemented well the experimental results on α-glucosidase and urease inhibitory effects of the compounds.Higher binding affinities and much more interaction networks were observed for active compounds in contrary to inactive ones.It was predicted with the docking studies that triazole and anisole moieties in the structure of the synthesized compounds contributed to the stabilization of corresponding enzymes through noncovalent interactions.     

On Fibonacci Quaternions

In this paper, we investigate the Fibonacci and Lucas quaternions. We give the generating functions and Binet formulas for these quaternions. Moreover, we derive some sums formulas for them.     

Numerical simulation of the unsteady flow over an elliptic cylinder at different orientations

A numerical method is developed for investigating the two‐dimensional unsteady viscous flow over an inclined elliptic cylinder placed in a uniform stream of infinite extent. The direction of the free stream is normal to the cylinder axis and the flow field unsteadiness arises from two effects, the first is due to the flow field development following the start of the motion and the second is due to vortex shedding in the wake region. The time‐dependent flow is governed by the full conservation equations of mass and momentum with no boundary layer approximations. The parameters involved are the cylinder axis ratio, Reynolds number and the angle of attack. The investigation covers a Reynolds number range up to 5000. The minor–major axis ratio of the elliptic cylinder ranges between 0.5 and 0.6, and the angle of attack ranges between 0° and 90°. A series truncation method based on Fourier series is used to reduce the governing Navier–Stokes equations to two coupled infinite sets of second‐order differential equations. These equations are approximated by retaining only a finite number of terms and are then solved by approximating the derivatives using central differences. The results reveal an unusual phenomenon of negative lift occurring shortly after the start of motion. Various comparisons are made with previous theoretical and experimental results, including flow visualizations, to validate the solution methodology. Copyright © 2001 John Wiley & Sons, Ltd.     

Synthesis and catalytic activity of novel xylyl‐linked benzimidazolium salts

The reaction of 1‐alkylbenzimidazole derivatives with o‐/p‐di(chloromethyl)benzene results in the formation of the new o‐/p‐xylyl‐linked bis(benzimidazolium) salts, 1 and 2, respectively. The salts were characterized by NMR spectroscopy and elemental analysis. The in situ prepared complexes derived from Pd(OAc)₂–1 and 2 exhibit catalytic activity (61–98%), to give the Heck coupling products of aryl bromides and styrene. Copyright © 2009 John Wiley & Sons, Ltd.     

Synthesis of novel rhodium‐xylyl linked N‐heterocyclic carbene complexes as hydrosilylation catalysts

Reaction of ortho‐xylylbis(N‐2,4,6‐trimethylbenzylimidazolinium); xylylbis(N‐butylimidazolinium) and para‐xylylbis(N‐2,4,6‐trimethylbenzylimidazolinium); xylylbis(N‐butylimidazolinium) salts with KOBu^t and [RhCl(COD)]₂ yields ortho‐ and para‐xylylbis{(N‐alkylimidazolidin‐2‐ylidene)chloro(η⁴‐1,5‐cyclooctadiene) rho dium(I)} complexes (2a–d). All compounds synthesized were characterized by elemental analysis and NMR spectroscopy, and the molecular structures of the 2a and 2d were determined by X‐ray crystallography. Triethylsilane reacts with acetophenone derivatives in the presence of catalytic amount of the new rhodium(I)–carbene complexes (2a–d), to give the corresponding silylethers in good yields (83–99%). Copyright © 2008 John Wiley & Sons, Ltd.     

Single-supplier/multiple-buyer supply chain coordination: Incorporating buyers’ expectations under vertical information sharing

We address the coordination problem in a single-supplier/multiple-buyer supply chain. The supplier wishes to coordinate the supply chain by offering quantity discounts. To obtain their complete cost information, the supplier exchanges his own cost parameters with buyers leading to vertical information sharing. The supplier thinks that the buyers, as they have access to supplier’s setup and holding cost information, may demand a portion of the anticipated coordination savings based on the partial information they hold about the cost structure of the entire supply chain. We model each buyer’s expectations based on her limited view of the entire supply chain which consists of herself and the supplier only. These expectations are then incorporated into the modeling of the supply chain, which results in a generalization of the traditional Stackelberg type models. We discuss alternative efficiency sharing mechanisms, and propose methods to design the associated discount schemes that take buyers’ expectations into account. In designing the discount schemes, we consider both price discriminatory and non-price discriminatory approaches. The study adds to the existing body of work by incorporating buyers’ expectations into a constrained Stackelberg structure, and by achieving coordination without forcing buyers to explicitly comply with the supplier’s replenishment period in choosing their order quantities. The numerical analysis of the coordination efficiency and allocation of the net savings of the proposed discount schemes shows that the supplier is still able to coordinate the supply chain with high efficiency levels, and retain a significant portion of the net savings.     

Streamwise oscillations of a cylinder beneath a free surface: Free surface effects on vortex formation modes

A computational study of a viscous incompressible two-fluid model with an oscillating cylinder is investigated at a Reynolds number of 200 and at a dimensionless displacement amplitude of A=0.13 and for the dimensionless forcing cylinder oscillation frequency-to-natural vortex shedding frequency ratios, f/f₀=1.5,2.5,3.5. Specifically, two-dimensional flow past a circular cylinder subject to forced in-line oscillations beneath a free surface is considered. The method is based on a finite volume discretization of the two-dimensional continuity and unsteady Navier-Stokes equations (when a solid body is present) on a fixed Cartesian grid. Two-fluid model based on improved volume-of-fluid method is used to discretize the free surface interface. The study focuses on the laminar asymmetric flow structure in the near wake region and lock-on phenomena at a Froude number of 0.2 and for the dimensionless cylinder submergence depths, h=0.25, 0.5 and 0.75. The equivorticity patterns and pressure distribution contours are used for the numerical flow visualization. The code validations in special cases show good comparisons with previous numerical results.